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There were 7,314 households of which 41.7% had children under the age of 18 living with them, 53.1% were married couples living together, 11.6% had a female householder with no husband present, 4.4% had a male householder with no wife present, and 31.0% were non-families.25.2% of all households were made up of individuals and 8.1% had someone living alone who was 65 years of age or older.In 1843, the first high school was opened by Caroline Humphrey, and by 1850 there was a Board of Education making annual reports to the voters.In 1837, the Ohio Gazetteer published that Marysville was a small post town consisting of a court house, a jail, forty-five dwelling houses, one tavern, three stores, one practicing physician, two attorneys and about 250 inhabitants.Males had a median income of ,973 versus ,427 for females. About 4.0% of families and 5.7% of the population were below the poverty line, including 5.3% of those under age 18 and 9.4% of those age 65 or over.The median price for a home in Marysville was 8,100 according to Census 2010.).Marysville's industrial roots can be traced back to many early companies.
The Church of Our Lady of Lourdes, a Roman Catholic Church, was constructed in 1866 at Water Street near the railroad station.The first steam-grist mill was erected in 1856 by Saxton and Casil. The Bank of Marysville was opened in 1854, the Farmer's Bank of Union County in 1868 located on the southeast corner of the square, and the People's Bank in 1874.In 1867, Miller & Snodgrass constructed a flour mill. In 1871, the Marysville Cheese Manufacturing Company was built on the east side. In 1840, Otway Curry, a poet of national fame and resident of Marysville, wrote the "Log Cabin Song." It would inspire the Log Cabin Campaign of William Henry Harrison, who would go on to win the Presidential election that year.The racial makeup of the city was 90.4% White, 4.5% African American, 0.3% Native American, 2.3% Asian, 0.1% Pacific Islander, 0.6% from other races, and 1.8% from two or more races.
Hispanic or Latino of any race were 1.8% of the population.
By 1865, Marysville had six dry goods stores, one hardware store, nine or ten groceries, a mill, a woolen factory, and most of the trades and professions. In 1877, the town council decided to build a city hall on the southeast corner of Main and South.